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Polymer Science Glossary

25 essential terms — because precise language is the foundation of clear thinking in Polymer Science.

Showing 25 of 25 terms

A polymer that can be decomposed by biological organisms into natural substances such as water, carbon dioxide, and biomass.

Related:PLASustainabilityPolymer Degradation

A conjugated polymer that can conduct electricity when doped with oxidizing or reducing agents.

Related:PolyacetyleneConjugationDoping

A polymer derived from two or more different types of monomers.

Related:Block CopolymerRandom CopolymerHomopolymer

The formation of covalent bonds between polymer chains, creating a network structure.

Related:ThermosetVulcanizationElastomer

The degree of structural order in a polymer; the fraction of the material composed of ordered, closely packed crystalline lamellae.

Related:SemicrystallineAmorphousMelting Temperature

A thermal analysis method that measures heat flow associated with phase transitions and reactions in polymers.

Related:Glass Transition TemperatureMelting TemperatureCrystallinity

The ratio of weight-average to number-average molecular weight (Mw/Mn), indicating the breadth of molecular weight distribution.

Related:Molecular WeightGPCLiving Polymerization

A polymer with rubber-like elasticity that can undergo large, reversible deformations.

Related:Cross-LinkingVulcanizationNatural Rubber

A polymer processing technique in which molten polymer is forced through a die to produce continuous shapes such as films, pipes, and fibers.

Related:Injection MoldingThermoplasticProcessing

An analytical technique that separates polymers by molecular size in solution to determine molecular weight distribution.

Related:DispersityMolecular WeightSize Exclusion Chromatography

The temperature at which an amorphous polymer transitions from a hard, glassy state to a flexible, rubbery state.

Related:AmorphousViscoelasticityMelting Temperature

A polymer formed from only one type of monomer unit.

Related:CopolymerMonomerRepeat Unit

A manufacturing process in which molten polymer is injected into a mold cavity, cooled, and ejected as a finished part.

Related:ExtrusionThermoplasticProcessing

A very large molecule, typically composed of thousands or more atoms, often a polymer.

Related:PolymerMolecular WeightDegree of Polymerization

A small molecule capable of reacting with other monomers to form a polymer chain.

Related:PolymerPolymerizationRepeat Unit

An additive that increases polymer flexibility by embedding between chains and lowering the glass transition temperature.

Related:Glass Transition TemperaturePVCFlexibility

A macromolecule composed of many repeating monomer units joined by covalent bonds.

Related:MonomerMacromoleculePolymerization

A physical mixture of two or more polymers that may be miscible or immiscible.

Related:MiscibilityCopolymerComposite

A material combining a polymer matrix with reinforcing fibers or fillers to achieve superior mechanical properties.

Related:Carbon FiberGlass FiberMatrix

The chemical reaction in which monomers are joined together to form a polymer.

Related:Addition PolymerizationCondensation PolymerizationMonomer

The relative stereochemistry of adjacent chiral centers within a polymer chain (isotactic, syndiotactic, or atactic).

Related:Ziegler-Natta CatalystIsotacticStereoregularity

A polymer that can be repeatedly softened by heating and hardened by cooling without chemical change.

Related:ThermosetMelting TemperatureExtrusion

A polymer that, once cured into a cross-linked network, cannot be remelted or reshaped.

Related:Cross-LinkingThermoplasticEpoxy

Behavior of materials that exhibit both viscous and elastic characteristics when undergoing deformation.

Related:CreepStress RelaxationGlass Transition Temperature

A chemical process in which natural or synthetic rubber is heated with sulfur to form cross-links, improving strength and elasticity.

Related:Cross-LinkingElastomerCharles Goodyear
Polymer Science Glossary - Key Terms & Definitions | PiqCue